Oxidation and Reduction
in Environmental Systems

Important topics:

Definition of oxidation and reduction

Electrochemical cells and measurement of redox potential

Electron activity and pE

Nernst equation and its relationship to the equilibrium constant and free energy

pE diagrams and how to interpret them

Redox equations and half reactions

You should be able to write and balance redox reactions, to determine Keq from the pE and vice versa, combine  half reactions into complete balanced reactions, and to interpret pE diagrams.

Chemistry topics:
(Basic chemistry topics which are applied in this chapter)

Homework assignment:

Chapter 4, Questions 1, 2, 5, 7, 10, 12

Discussion topic for next several weeks:

Changes in either the pH or pE of a natural body of water will have various effects on the biota and the overall condition of the lake or river. Give examples of such situations, including a discussion of the chemistry involved in the changes. Look at the extended consequences where possible. As usual, comment on the postings, adding to their completeness.

Look for sites on the Internet which discuss water quality. Rate these sites as to the completeness, accuracy and clarity of the information given. Post these to our discussion page with URLs and your discussions. Look at the sites proposed by your colleagues and see if you agree or disagree with their evaluations. Be sure to add your agreement or disagreements to the discussion.

Overhead copies

Homework solutions

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